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Heat-acid curdling
Technique

Heat-acid curdling

pH 4.6 · 85 °C

Cheesemaking without rennet. Curdling is an accident in a yoghurt soup; here it is the product. Heat and acid together collapse the casein, and the drained curd is çökelek.

What is happening

The mechanism

Casein micelles normally carry a repelling negative charge, which is what keeps them suspended in milk. Acid neutralises it; at pH 4.6 — casein’s isoelectric point — the repulsion ends and the particles stick together. Heat speeds it and tightens the net. The difference from rennet cheese shows in the texture: rennet cuts the casein into a smooth, elastic gel, while acid collapses it into a grainy, crumbling curd. That is why çökelek crumbles and kaşar stretches.

The numbers

The thresholds that define it

“Medium heat” is not a technique. Every line below is a point where something starts or stops.

  1. pH 4,6 Where casein collapses. No curd forms until the acid takes it below this.
  2. 85 °C Where the curd gathers. A disaster in a yoghurt soup, the objective here.
  3. 72 °C Whey protein denatures here and joins the curd, so the yield goes up.
Without a thermometer

How to read it by hand

Draw a spoon through it: when a clear greenish liquid and a white curd have visibly parted, it is there. If the liquid is still milky white, there is not enough acid.

When it goes wrong

The three mistakes people make

01 Very little curd
Why

Skimmed milk, or not enough acid. The whey is still carrying protein.

What to do

Add more acid and take it to 72 °C: the whey protein denatures too and joins the curd.

02 The curd is rubbery
Why

Too hot for too long. The protein net over-tightened.

What to do

Do not pass 85, and take it off the moment the curd gathers.

History

Where it comes from

Heat-acid curdling predates rennet and is probably the first cheese anybody made: soured milk brought near a fire separates on its own. In Anatolia çökelek, lor, keş and sürk are regional names for this one technique. Sürk is the most heavily spiced of the family: the curd is kneaded with pepper paste and za’atar and matured in cones.